Lydia Rodate-Quayle is a partner of Mike's. She provides Walter and Jesse with resources to make meth. She is the Head of Logistics at Madrigal Electromotive. She appears in the show for a short period of time, but has a big role with the meth buisness.
Gustavo Fring is the owner of a chain for a fast-food restaurant in the Southwest of America, Los Pollos Hermanos. Gustavo is very careful with his work in the drug buisness. He is always one step ahead of people. He works with the police and sponsors them, without any of them knowing he is a major drug
Mike Ehrmantraut is a grandfather, and is a partner of Gustavo Fring. He helps clean up Jesse's and Walter's messes. He is a former cop in Philly. We later find out that he passes away, which was unexpected.
Saul Goodman is the lawyer for Combo, Badger, Skinny Pete, Jesse, and Walter. He plays a small part in Walter and Jesse's meth buisness. He hooks them up with a better lab by partnering them up with Gustavo Fring and Mike Ehrmantraut. They give Jesse and Walter more resources and a better place to cook their meth.
Steve Gomez is a friend of Hank Schrader, who also works for the DEA.
Hector Salamanca is the Uncle of Tuco, and father of Leonel and Marco Salamanca. He used to work in the cartel in Mexico, but later moved into a elderly home. He plans to take down Gustavo Fring with Walter. He can't speak so he can only answer by using a bell.
Leonel and Marco Salamanca show up in the show to avenge their cousin, Tuco. They are the sons of Hector Salamanca. They want to murder Walter White for killing Tuco, but what they don't know is that DEA agent Hank Schrader is the one that shot and murdered him. They end up targeting Hank, but Hank was able to take them both out.
Tuco Salamanca, nephew of Hector Salamanca, and cousin of Leonel and Marco Salamanca. After Krazy-8 passes away, Tuco Salamanca takes his place as the distributor for New Mexico. He works with Walter and Jesse after he falls in love with their product. He later dies to Hank Schrader, who has been targeting Tuco for a long time.
Krazy-8, the cousin of Emilio, is the first main antagonist in the show. He is the main distributor in New Mexico that works with Jesse and Tuco Salamanca. He attempts to kill Walter and Jesse, but luckily Walter and Jesse get their way out of it. Eventually, Krazy-8 is locked in Jesse's basement and murdered by Walter and Jesse.
Emilio Koyama appears in the show for a short period of time. He is one of the two first main antagonists of the show. He was friends with Jesse Pinkman, before Emilio and his cousin tried to kill Jesse and Walter. He gets intoxicated while Walter shows him how to cook the meth he made, which allowed for Jesse and Walter to avoid death. While he is getting intoxicated he eventually dies.
Skinny Pete, Combo, and Badger are the friends of Jesse Pinkman. They each are drug addicts and are loyal to Jesse. There are some parts of the show where they work Jesse has a distributor for the meth Jesse and Walter cooked.
Marie Schrader is the wife of Hank Schrader, sister of Skyler White, sister-in-law of Walter White, and aunt of Walter White jr./Flynn and Holly White. She works as a radiologic technologist. She has a habit for shoplifting, and supports Skyler throughout the show.
Hank Schrader is the husband of Marie Schrader, brother-in-law for both Skyler and Walter White, and the uncle of Walter White jr./Flynn and Holly White. Hank Schrader is a DEA agent, Drug Enforcement Administration, and later becomes the head of the DEA in Albuquerque. For over a year, Hank has been chasing down Heisenberg.
Holly white is the daughter of Walter and Skyler White, neice of Hank and Marie Schrader, and sister of Walter White jr./Flynn.
Walter White jr, or Flynn, is the son of Walter and Skyler White, nephew of Marie and Hank Schrader, and the only brother of Holly White. Walter jr. is a crippled child, in real life too, and has a stutter.
Skyler White, the wife of Walter White, is a very nosy person, but I don't blame her. Her suspicions get high when Walter starts to get home late. She has two kids; Walter White jr./Flynn and Holly White. She has a sister, Marie White, and a brother-in-law, Hank.
Jesse Pinkman, another main character in the show, is Walter White's former student and partner in the drug buisness. He takes care of hooking people up with the meth Walter cooks, he is a drug addict which says a lot about him. His family doesn't want him around because they don't want Jesse to influence his younger brother, Jake Pinkman.
Walter white, the main charcter of Breaking Bad, is diagnosed with cancer. As a chemistry high school teacher, he doesn't earn that much money, and he paniced for who was going to provide for his family. He uses the name Heisenberg for his street name. His family includes: Walter White jr. or Flynn(son), Skyler White(wife), Holly White(daughter), Hank Schrader(brother-in-law), and Marie Schrader(sister-in-law).

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